Solvothermal Alcoholysis Method for Recycling High-Consistency Silicone Rubber Waste

In this work, we investigated the potential use of high-consistency silicone rubber (SR), which is a synthetic solid material used in numerous industrial applications, to produce a range of liquid alkoxysiloxane derivatives R(OSiMe 2 ) x OR, with x = 1 ( P 1 ), 2 ( P 2 ), 3 ( P 3 ), and 4 ( P 4 ). We describe a simple and convenient solvothermal alcoholysis method for the chemical recycling of post-consumer SR in the presence of fatty alcohols under catalyst-free or catalytic conditions. This process proceeds easily both without and with a catalyst. Alkali-metal aryloxides supported by a methylsalicylato ligand (MesalO) gave the highest conversions of SR to products P 1 – P 4 . Magnesium and zinc aryloxides enabled efficient conversions of products P 2 – P 4 to P 1 . Binary metal catalysts of general formula M 2 M′ 2 (MesalO) 6 (M = Mg or Zn; M′ = Li, Na, or K), which had a combination of the catalytic properties shown by alkali-metal aryloxides and magnesium/zinc aryloxides, were produced and used to synthesize P 1 – P 4 . The results show that magnesium–sodium/potassium aryloxides had the best catalytic activities. Their use led to the formation of two dominant products, namely, P 1 and P 2, with conversion yields of 79 and 17%, respectively. Particular emphasis is placed on the operating conditions and high activity of the catalyst used. Key factors that affect the catalytic activity and reaction mechanism are also highlighted.