Key points are not available for this paper at this time.
Controlling the structure of halide perovskites through component engineering, and thus revealing the changes in luminescence properties caused by the conversion of crystal structure, is of great significance. Herein, we report a controllable synthetic strategy of three-dimensional (3D) Cs2KInCl6 and zero-dimensional (0D) (Cs/K)2InCl5(H2O) halide perovskites by changing the Cs/K feed ratio. 3D Cs2KInCl6 double perovskites are obtained at the Cs/K feed ratio of 1:1, while 0D (Cs/K)2InCl5(H2O) perovskites are formed at the Cs/K feed ratio of 2:1. Further, a reversible crystal structure transformation between 3D Cs2KInCl6 double perovskites and 0D (Cs/K)2InCl5(H2O) perovskites can be achieved by subsequent addition of metal-salt precursors. In addition, the emission efficiency of two perovskite structures can be greatly boosted by breaking the forbidden transition through Sb doping, and as a result, a novel green/yellow reversible emission switch is generated. Meanwhile, the relationship between perovskite structure and luminescence mechanism has been systematically revealed. These environmentally stable halide perovskites have great potential to be applied in optoelectronic devices.
Chang et al. (Tue,) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: