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Cathode coating is a key technology in sulfide-based all-solid-state batteries (ASSBs). The coating serves as a protector, suppressing side reactions at the sulfide/cathode active material interface. Lithium niobate (LiNbO3) is a well-known coating material. In this study, sulfide-based ASSBs, which were uncoated and surface-coated with LiNbO3, are subjected to cell operation testing and electrochemical impedance spectroscopy (EIS) in a low-temperature environment (i.e., −60 °C), where a commercial liquid-type lithium-ion battery (LIB) is unable to operate because of partial freezing and significant viscosity increase. Unlike liquid-type LIBs, the coated and uncoated ASSBs successfully discharge at −60 °C, emphasizing their applicability in low-temperature environments. The coated ASSB exhibits better low-temperature performance than the uncoated one. In the absence of coating, the deconvoluted EIS resistance data show an increase in some resistance components at low temperature.
Yusuke Morino (2021) studied this question.