Growth of Lead Halide Perovskite Nanocrystals: Still in Mystery

Lead halide perovskite nanocrystals with different halide ions can lead to color-tunable emissions in visible window with near-unity photoluminescence quantum yields. Extensive research has been carried out for optimizing the synthesis of these nanocrystals for the last 6 years, and thousands of research papers have been reported. However, due to the ionic nature, these nanocrystals formed instantaneously and hence, their growth kinetics could not be established yet. In most of the reactions, the formation mechanism typically followed one reaction for one size or shape principle, and their dimension tuning was achieved predominantly with thermodynamic control. There is no clear evidence yet on the decoupling growth from nucleations and monitoring their growth kinetics. Hence, the progress of understanding the fundamentals of crystal growth faced road blocks for these halide perovskite nanocrystals. Keeping eyes on all such reports on one reaction for one size and one reaction for tunable size of the most widely studied CsPbBr3 nanocrystals, in this perspective, details of their size tunability are analyzed and reported. In addition, comparison of the classical mechanism, obstacles for establishing secondary growth, and possible road maps for controlling the kinetic parameters of formation of these nanocrystals are also discussed.