Development of Pure Green Thermally Activated Delayed Fluorescence Material by Cyano Substitution

is reported. The key to success is introduction of cyano groups into a blue-emitting MR-TADF material (ν-DABNA), which causes remarkable bathochromic shift without a loss of color purity. The organic light-emitting diode employing it as an emitter exhibits green emission at 504 nm with a small full-width at half-maximum of 23 nm, corresponding to Commission Internationale d'Éclairage coordinates of (0.13, 0.65). The device achieves a high maximum EQE of 31.9% and successfully suppresses the efficiency roll-off at a high luminance.