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A metal- and additive-free consecutive photoinduced electron transfer (ConPET) photocatalytic system enables highly efficient, redox-neutral ketyl radical coupling and cyclization of N-aryl acrylamides with carbonyls at 100% atom economy. Novelty: ClaimNovelty.METHODOLOGICAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

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January 1, 2022

Redox-neutral ketyl radical coupling/cyclization of carbonyls withN-aryl acrylamides through consecutive photoinduced electron transfer

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Abstract

Redox-neutral ketyl couplings: a metal- and additive-free ConPET photocatalytic system allows highly efficient coupling/cyclization of N -aryl acrylamides and carbonyls with formal 100% atom economy.

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