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The unprecedented photorearrangement of nitro-perylenediimide (NO2-PDI) to nitrito-perylenediimide (ONO-PDI) is shown to occur through a cyclic six-membered transition state triggered by visible-light excitation.
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Aniruddha Mazumder
Indian Institute of Science Education and Research Thiruvananthapuram
Ebin Sebastian
University of Cambridge
Mahesh Hariharan
Indian Institute of Science Education and Research Thiruvananthapuram
Chemical Science
Indian Institute of Science Education and Research Thiruvananthapuram
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Mazumder et al. (Sat,) studied this question.
synapsesocial.com/papers/6a1b4db4237e31891342ad21 — DOI: https://doi.org/10.1039/d2sc02979k