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ZSM-35, synthesized using dioxane as the structure-directing agent, featured preferential population of Al atoms at the T4 site in the 8-MR pore, and the Brønsted acid site, thus generated, catalyzed DME carbonylation actively and stably.
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Zhiping Xiong
Guodong Qi
Luyi Bai
Catalysis Science & Technology
Chinese Academy of Sciences
University of Chinese Academy of Sciences
Dalian Institute of Chemical Physics
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Xiong et al. (Sat,) studied this question.
www.synapsesocial.com/papers/69db1e7c3d9adb00e7684509 — DOI: https://doi.org/10.1039/d2cy01112c