Key points are not available for this paper at this time.
Time-resolved photoluminescence (TRPL) is an effective experimental technique to study charge carrier dynamic processes in halide perovskites on different time scales. In the past decade, several models have been proposed and employed to study the TRPL curves in halide perovskites, but there is still a lack of systematic summarization and comparative discussion. Here, we reviewed the widely employed exponential models to fit the TRPL curves, and focused on the physical meaning of the extracted carrier lifetimes, as well as the existing debates on the definition of the average lifetime. Emphasis was placed on the importance of the diffusion process in the carrier dynamics, especially for the halide perovskite thin films having transport layers. The solving of the diffusion equation, using both analytical and numerical methods, was then introduced to fit the TRPL curves. Furthermore, the newly proposed global fit and direct measurement of radiative decay rates were discussed.
Chen et al. (Sun,) studied this question.