An updated fluorescence emission model of CO+ for cometary science

ABSTRACT A new CO^+ fluorescence emission model for analysing cometary spectra is presented herein. Accurate line lists are produced using the PGOPHER software for all transitions between the three electronic states (X ², A ², B ²) with vibrational states up to v_ max = 9, 8, 6, respectively, and maximum rotational states with rotational quantum numbers N 20. As a result of improved molecular constants and theoretical transition rates, an expansion of the utilized solar spectrum into the infrared, and the substantial expansion of the included rovibronic states, the model provides an update of the fluorescence efficiencies of the CO^+ cation. The dependencies on heliocentric velocity and distance are explicitly included. We report, for the first time, quantification of the fluorescence efficiencies for the ground state rovibrational transitions of CO^+ and predict the positions and relative intensities of CO^+ lines in windows accessible to both ground- and space-based observatories. The computed fluorescence efficiencies show excellent agreement with UV/optical observations of both C/2016 R2 (PanSTARRS) and 29P/Schwassmann-Wachmann 1. The updated fluorescence efficiencies allow for revised N₂/CO abundances for comets 1P/Halley, C/1987 P1 (Bradfield), and C/2016 R2 (PanSTARRS), which can change by up to 30 per cent when accounting for recent improvements to CO^+ and N₂^+ fluorescence efficiencies. The model code, input files, and fluorescence efficiencies are publicly available and distributed on permanent archives for future uses in cometary analyses.