Nanostructured ZnO with Tunable Morphology from Double-Salt Ionic Liquids as Soft Template

ZnO nanostructures with tunable morphology were synthesized by the hydrothermal method from two ionic liquids (ILs), 1-ethyl-3-methylimidazolium acetate C2mimCH3CO2 and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide C2mim(CF3SO2)2N and their corresponding double-salt ILs (DSILs). ILs served as soft templates. DSILs were noted for the production of smaller particle size along with uniformity compared to their pure IL counterparts. A changeover of the shape of ZnO from nano-prism to a hexagonal disk-like structure was observed with the addition of C2mimCH3CO2 in the medium during synthesis while nano-dice- and rod-shaped particles were obtained from C2mim(CF3SO2)2N. The effect of concentration of both ILs was explored for the variations of size and shape, and at high concentrations, the morphology was distinct and sharp with uniform size in each case. The synthesized products exhibited excellent phase (wurtzite) purity and polycrystalline nature. The smallest crystallite size was acquired from DSILs, indicating the advantageous effect of the dual anions. The selective adsorption effect of C2mimCH3CO2 on certain facets promoted the growth of ZnO clusters along the 1010 direction, while C2mim(CF3SO2)2N favored the growth along the 0001 direction. Consequently, DSILs rendered interpenetrating hexagonal disks due to the combined action of the anions for controlling the shape. The band gap energies of the nanoparticles (NPs) were consistent with the distribution of size. Extremely strong red emission and negligible UV emission for the synthesized ZnO NPs demonstrate their potential in the advancement of optoelectronic devices.