High‐Adhesion, Weather Resistance, Reusable PAM/Gly/Gel/TA/Fe3+ Biopolymer Dual‐Network Conductive Hydrogel for Flexible Bioelectrode

Abstract Conductive hydrogel is considered a promising wearable sensor material. Developing flexible conductive hydrogel sensors with stretchability, adhesion, and stability remains challenging. In this study, a transparent, self‐adhesive, antifreeze, anti‐UV, stretchable, conductive, and reusable hydrogel with polyacrylamide/glycerol/gelatin/tannic acid/Fe 3+ (PGGT‐Fe 3+ ) structure is successfully constructed through a simple one‐pot polymerization method. The PGGT‐Fe 3+ hydrogel is composed of dual networks of polyacrylamide and gelatin for organic cross‐linking, using water/glycerol as the dispersion medium, and incorporates a viscous substance: tannic acid, and a conductive substance: metal ions (Fe 3+ ). Due to the introduction of the abundant amino, carboxylic acid, and hydroxyl functional groups on gelatin and tannic acid, the PGGT‐Fe 3+ hydrogel exhibits excellent and repeatable adhesion capabilities on various surfaces (including glass, metal, plastic, and pigskin) with maximum adhesion strength of 98 kPa when attached to pigskin. Furthermore, based on the stable conductive network and high conductivity, the hydrogel not only exhibits strain sensitivity, fast response, and stability but also can stably collect epidermal bio signals. In conclusion, this work provides a new approach to the design and development of next‐generation multifunctional conductive hydrogels and opens up vast possibilities for their applications in the flexible electronics field.