Investigation of Morphology, Optical and Electronic Ac Conduction of the Olivine Manganite Compound: NaMnPO4

Abstract The evolution of multifunctional materials is an outstanding research area, which aims to improve the versatility of materials according to their broad domains of usage. Focus interest was paid here to the orthophosphate compound, in particular, the olivine NaMnPO 4 material. This compound was synthesized by a solid‐state method and investigated using numerous techniques. Primary room‐temperature structural analysis evidences the sample synthesized in the orthorhombic structure and its phase purity. The sample‘s average grain size was calculated to be around 420 nm. Further, the band gap for our material was found to be (E g =4.4 eV) by optical analysis of UV‐visible spectroscopy, revealing that our compound is a potential candidate for optoelectronic applications. The electrical behavior study‘s main results confirm the ferroelectric character of the sample and support the aim of deepening the knowledge of the material according to its thermally stimulated conduction processes through impedance spectroscopy. Electrical studies revealed the dominant transport processes across various temperature and frequency ranges, leading to the NSPT model. The frequency dependency relates to frequency‐dispersive dielectric spectra, conduction mechanisms, and relaxation phenomena. The obtained results show perspective and suggest that the material under study has a wide range of potential electronic applications.