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Abstract Triplet‐triplet fusion (TTF) can effectively transfer triplet excitons to singlet energy level and exhibit good stability, making it widely used in blue fluorescence organic light emitting diodes (OLEDs) for practical application. However, the efficiency of the resulting blue fluorescence OLEDs is still fundamentally limited. Herein, this work introduces a hot exciton efficiency enhancement layer (EEL) between TTF emissive layer and electron‐transporting layer for the first time. It can be found that the triplet excitons are greatly utilized by the efficient hot exciton EEL. As a result, a high efficiency blue fluorescence OLED is successfully developed, exhibiting a maximum external quantum efficiency of 15.2% at the luminance of 4068.0 cd m −2 , achieving a breakthrough in the efficiency of blue TTF‐OLEDs. Transient electroluminescence (TrEL) measurements and detailed theoretical calculations confirm the key role of the effective hot exciton process from the high‐lying triplet energy level (T n , n ≥ 2) to S 1 via a reverse intersystem crossing (hRISC). Furthermore, the device lifetime is also greatly improved owing to the fast and efficient hRISC in the introduced hot exciton EEL. This work has important guiding significance for constructing high efficiency blue fluorescence OLEDs by introducing hot exciton molecules.
Xie et al. (Tue,) studied this question.