Theoretical insights into dopamine photochemistry adsorbed on graphene-type nanostructures

surface-to-molecule (SMCT). The difference between the two cases is given by the presence of an energetically low-lying unoccupied orbital (LUMO+1) that allows charge transfer from the surface to the molecule in the case of DAQ. However, it was also shown that the fingerprints of excited electronic states associated with the adsorbed molecules cannot be seen in the spectrum, as they are mostly suppressed by the characteristic spectral shape of graphene.