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Described herein is a dirhodium(II)-catalyzed silylation of propargyl esters with hydrosilanes, using tertiary amines as axial ligands. By adopting this strategy, a range of versatile and useful allenylsilanes can be achieved with good yields. This reaction not only represents a S
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Wendeng Li
South China University of Technology
Rui Wu
Hao Ruan
China Institute of Atomic Energy
Angewandte Chemie International Edition
Peking University
Central South University
South China University of Technology
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Li et al. (Tue,) studied this question.
synapsesocial.com/papers/68e642a9b6db6435875d4c1c — DOI: https://doi.org/10.1002/anie.202409332