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An intriguing phenomenon in non-equilibrium quantum thermodynamics is the asymmetry of thermal processes. Relaxation to thermal equilibrium is the most important dissipative process, being a key concept for the design of heat engines and refrigerators, contributing to the study of foundational questions of thermodynamics, and being relevant for quantum computing through the process of algorithmic cooling. Despite the importance of this kind of processes, their dynamics are far from being understood. We show that the free relaxation to thermal equilibrium follows intrinsically different paths depending on whether the temperature of the system increases (heating up) or decreases (cooling down), being faster in the first case. Our theory is exemplified using the recently developed thermal kinematics based on information geometry theory, utilizing three prototypical examples: a quantum two-level system, the quantum harmonic oscillator, and a trapped quantum Brownian particle, including both analytic results and numerical simulations. For this, we have extended the thermal kinematic approach to open quantum systems. Additionally, we offer a simple theoretical explanation in the case of a two level system and a more general picture for the other two systems based on the spectral decomposition of the Liouvillian and the spectral gap of reciprocal processes.
Tejero et al. (Fri,) studied this question.