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A palladium-catalyzed asymmetric tandem Heck and carbonylation of bisallyl-phosphine oxides has been developed. This desymmetrization process provided an efficient route to the simultaneous synthesis of a chiral P-stereogenic center and a chiral quaternary carbon stereocenter in good yields with good diastereo- and enantioselectivities.
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Zhou et al. (Fri,) studied this question.
www.synapsesocial.com/papers/68e613bcb6db6435875a6405 — DOI: https://doi.org/10.1021/acs.orglett.4c01863
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:
Hengrui Zhou
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Organic Letters
China Pharmaceutical University
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