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Long-chain polyamides (polyethyleneamides) were prepared from polyethylenes bearing in-chain carbonyl groups (polyethyleneketones) by the oxime formation and successive Beckmann rearrangement. (Diethylamino)sulfur trifluoride (DAST) was utilized as a promoter, which allowed mild conversion of the oxime group in spite of low solubility of the polymers. The polyethyleneamide exhibited different tensile property compared to a commercial HDPE.
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Lu et al. (Wed,) studied this question.
www.synapsesocial.com/papers/68e60be9b6db64358759edb0 — DOI: https://doi.org/10.1002/anie.202410849
Yipu Lu
Kohei Takahashi
Jian Zhou
Angewandte Chemie International Edition
The University of Tokyo
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