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Abstract Fluorenones are suitable candidates for negolytes in flow batteries, as they demonstrate the ability to store 2 electrons, and can achieve reversibility, solubility, and stability with appropriate molecular design. However, limitations persist such as the use of alkaline media, high redox potentials, and a limited scope for optimization. Herein, azoniafluorenones is reported as a novel class of negolytes. They can be readily accessed in a highly modular fashion from inexpensive commercially available materials (e.g., boronic acids). Variations in the substitution patterns reveal the 3‐substituted N ‐alkylated AZON3, which demonstrates excellent solubility at neutral pH (1.64 m ) with two low reversible redox potentials (−0.31 and −0.58 V vs Ag/AgCl). AZON3 exhibits high stability when evaluated at high concentration in a neutral supporting electrolyte (1 m in 3 m KCl), paired with BTMAP‐Fc on the positive side. Capacity retentions of 99.95% and 99.91% per cycle (99.35% and 99.21% per day) are achieved when cycling with 1 and 2 electrons, respectively, coupled with high volumetric capacity of 46.4 Ah L −1 (87% of capacity utilization).
Artault et al. (Thu,) studied this question.