Key points are not available for this paper at this time.
Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has received tremendous attention in the energy field owing to its high conductivity, ease of processing, biocompatibility, and low cost-effectiveness. Combining PEDOT:PSS and photonic crystals (PCs) is expected to promote the development of high-performance optoelectronic devices. The conductivity of PEDOT:PSS at present can only be measured through specific equipment, and the visualization of optoelectronic integration still remains a challenge. In this study, various patterned PEDOT:PSS inverse opal (PEDOT:PSS-IO) films are constructed by associating the conductivity of PEDOT:PSS with the structural color of PCs based on the synergistic effect of morphology/conformation transition, which achieves the visualization of optoelectronic integration. Morphology transition of the PEDOT:PSS-IO film alters from the interconnected to gradual closure pore structure, accompanied by an unusual blueshift of the stopband, which can be attributed to the collapse/reconstruction of the frame of the PEDOT:PSS-IO film. Conformation transition of PEDOT chains converts from the benzene to quinone structure, accompanying an enhancement of conductivity, which resulted from PSS removal and secondary doping. Under the induction of a polar solvent, the PEDOT:PSS-IO film brings the changes in optical/electrical dual-signals based on the synergistic effect of morphology/conformation transition. This phenomenon can be developed for the creation of a conductive PC pattern by using a polar solvent (water) as an ink, which is beneficial for the visualization of optoelectronic integration. This work provides essential significance for the fabrication of functional optoelectronic devices.
Wu et al. (Sat,) studied this question.