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Abstract Ferroelectric nematic liquid crystals (N F LCs) are distinguished by their remarkable polarization characteristics and diverse physical phenomena, sparking significant interest and excitement within the scientific community. To date, over 150 N F LC molecules are developed; however, there are no reports regarding straight linear polar molecules with a parallel alignment of the permanent dipole moment and the molecular axis. The straight polar mesogen nBOE exhibits an enantiotropic N F phase with a wide temperature window (up to 100 K) despite having a longer alkyl chain (up to n = 6) than the critical alkyl chain length of conventional models. Interestingly, nBOE with a medium‐length alkyl chain displays an exotic phase sequence of N F – HC N F –SmX F during the elimination of positional displacement among adjacent molecules. Furthermore, the reflective color modulation of the HC N F LC over the entire VIS‐NIR spectral regime by ultralow E ‐field (up to 0.14 V µm −1 ) is demonstrated.
Nishikawa et al. (Mon,) studied this question.