August 9, 2024Open Access

An Enzymatic Oxidation Cascade Converts δ-Thiolactone Anthracene to Anthraquinone in the Biosynthesis of Anthraquinone-Fused Enediynes

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Abstract

Anthraquinone-fused enediynes are anticancer natural products featuring a DNA-intercalating anthraquinone moiety. Despite recent insights into anthraquinone-fused enediyne (AQE) biosynthesis, the enzymatic steps involved in anthraquinone biogenesis remain to be elucidated. Through a combination of

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Authors

Guang‐Lei Ma

Women's Hospital, School of Medicine, Zhejiang University

Wan-Qiu Liu

ShanghaiTech University

Huawei Huang

Yangtze Optical Electronic (China)

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JACS Au

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Nanyang Technological University

Zhejiang University

ShanghaiTech University

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An Enzymatic Oxidation Cascade Converts δ-Thiolactone Anthracene to Anthraquinone in the Biosynthesis of Anthraquinone-Fused Enediynes

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