Nonalternating π-System Mediated Spin Coupling in Azulene Nitronyl Nitroxide Diradicals

To explore the distinctions in spin coupling between the molecular bridges of alternating and nonalternating π-systems, we synthesized a pair of isoelectronic compounds, namely, 2,6-Na-NN and 2,6-Az-NN, by utilizing naphthalene and azulene (naphthalene = Na and azulene = Az) as the bridges, respectively. Moreover, we conducted assessments to predict the coupling paths for nonalternating azulene. Variable-temperature EPR (VT-EPR) and SQUID results consistently reveal that both 2,6-Na-NN and 2,6-Az-NN exhibit antiferromagnetic coupling interactions, with coupling constants of J(2,6-Na-NN) = −22.3 cm–1 and J(2,6-Az-NN) = −30.1 cm–1, respectively. Density functional theory computations support these discoveries by revealing negative coupling constants (J < 0) and the spin densities population of the diradicals are observed to delocalize into the molecular bridges. This work suggests the most suitable coupling path for 2,6-Az-NN. In addition, we have investigated the potential spatial resistance of the diradicals in conjunction with single-crystal data. Theoretical calculations underestimating the torsion angle of the diradicals and overestimating the value of the magnetic coupling provide an explanation for this phenomenon. The final experimental results and theoretical calculations show that the 2,6-Az-NN coupling path prefers short paths.