Key points are not available for this paper at this time.
Functionalizing colloidal particles with oppositely charged surfactants is crucial for stabilizing emulsions, foams, all-liquid structures, and bijels. However, surfactants can reduce the attachment energy, the driving force for colloidal self-assembly at interfaces. An open question remains on how the inherent interfacial activity of cationic surfactants influences the interfacial rigidity of particle-laden interfaces. We hypothesize that charge screening among cationic surfactants regulates the rigidity of oil/water interfaces by reducing the attachment energy of nanoparticles.
Siegel et al. (Thu,) studied this question.