Distribution, source apportionment and ecological risk assessment of heavy metals in Limbe River sediments, Atlantic Coast, Cameroon Volcanic Line

The objective of this research was to assess sediments contamination, provenance and metal pollution using single and complex pollution indicators. Limbe River sediment samples were analysed using Inductively Coupled Plasma—Mass Spectrometry. The Limbe River sediments exhibit high content in Fe2O3 sourced from haematization of basaltic rocks. The concentration of Cd, Co, Cr, Mn, Ni, Pb, Sn, Sr, V and Zn exceed upper continental crust and local baseline values for heavy metals. Correlation matrix analysis indicates the presence of common input sources and similar geochemical characteristics of heavy metals. Contamination factor (CF: 0.01–10.34), contamination degree (Cdeg: 14.91–36.57), pollution load index (PLI: 0.84–1.77), and nemerow integrated pollution index (NIPI: 0.2–1.7) indicates significant to high levels of contamination. The enrichment factor (EF: 0–5.67) and geo-accumulation index (Igeo: -7.55–2.59), suggests moderate to significant metal pollution of the Limbe River ecosystem, suggesting potential ecological effects. Modified hazard quotient (mHQ: 0.082–6.35) and toxic risk index (TRI: 10.49–27.43), indicates low to extreme pollution severity and high toxicity risks of heavy metals to the aquatic ecosystem fauna and flora. Primarily anthropogenic activities and secondary lithogenic provenance is attributed to sediments contamination and metals pollution. This study suggests that a greater emphasis should be placed on monitoring various provenances of metals entering the aquatic ecosystem from anthropogenic practices. The study emphasizes the significance of continual protection of aquatic ecosystem and biological resources and adaptive management. The development of reasonable goals for monitoring and remedial programmes can be aided by this data.