Experimental Investigation of Sulfur and Nitrogen Oxide Emissions and Corrosion Propensity During the Combustion of Coals and Biomass Fuels

The increasing use of biomass in Indonesian coal-fired power plants, mainly through co-firing, presents challenges due to different fuel characteristics, which can affect gas emissions, ash deposition, and combustion efficiency. This study assesses flue gas emissions (SO2 and NOx) and corrosion tendencies of various biomass types and coal. The study begins with characteristic testing and ash analysis of coal and biomass samples, including proximate, ultimate, and calorific value analyses, to determine their suitability as fuels. Preliminary calculations predict flue gas emissions and ash deposit formation, followed by laboratory-scale combustion experiments using a DTF to assess flue gas and ash deposit characteristics. The results show that sulfur in biomass is converted to the gas phase up to 99%, while in coal, it is converted up to 95% at high temperatures. NOx levels are primarily affected by the nitrogen contents of the fuels; for instance, Coal-B at 0.88 wt% produces less NOx than solid recovered fuel (SRF) and refused derived fuel (RDF) with 1.73 wt% and 1.51 wt%, respectively, yet still generates higher emissions than the other three biomass types. In general, wood chips (WC), rise husk (RH), and palm kernel shell (PKS) emit 30–80% less flue gas compared to coal. However, ash deposition results indicate that PKS, SRF, and RDF exhibit corrosion tendencies due to the dominance of albite (NaAlSi3O8) in the mineral phase. Additionally, the high chlorine content in SRF (0.544 wt%) and RDF (0.224 wt%) leads to the formation of sticky ash deposits, which potentially impact heat transfer surfaces. These findings contribute to identifying suitable biomass types for both co-firing or dedicated combustion in coal-fired power plants.