Construction of Multiple Five‐Membered Rings in Dibenzog,pchrysene Core for the Synthesis of a Nona‐cycle Buckybowl

C60‐fragmentary bowl‐shaped molecules, commonly referred to as “buckybowls”, are provocative compounds, and their inviting functions based on the non‐planar pi‐conjugation are expected. Yet, achieving synthesis of some kinds of the curved structure remaining challenging. Herein we report skeletal construction of a nonacyclic buckybowl that is synthetically unachievable heretofore, namely, 3,10‐dihydroindeno7,1,2‐pqr‐as‐indaceno3,2,1,8,7‐defghichrysene. The key to success was solution‐compatible process in which a multiple substituted dibenzog,pchrysene is amenable to threefold formation of five‐membered rings at its periphery. The resulting scheme here, coupled with the gently curved scaffold, offers a new insight into the solution‐phase synthesis of curved and twisted polyarenes.