Converting Waste Polyethylene Terephthalate to High Value Monomers by Synergistic Catalysts

Waste plastics accumulation, such as commonly used polyethylene terephthalate (PET), has caused serious environmental pollution and resource squander. Glycolysis is a reliable closed‐loop PET recycling method, which limited by the high cost and complex catalysts preparation processes. Here we report a simple synergistic catalytic strategy by premixing zinc acetate and cheap alkalis in ethylene glycol, which could achieve complete glycolysis at 180 ℃ within 2 hours, and a bis(hydroxyethyl) terephthalate (BHET) yield of 86.4%. This may be attributed to the free hydroxide ions not only enhancing the nucleophilicity of oxygen in ethylene glycol and making it easy to attack carbonyl groups, but also accelerating the swelling and dissolution of PET. Meanwhile, the in‐situ generated Zn‐glycolate and zinc oxide nanoparticles (ZnO NPs) activated the oxygen in the carbonyl group, making the carbon cations more electropositive. Further recycling experiments and techno‐economic analysis indicated that our synergistic strategy significantly reduced industrial costs and expected to achieve large‐scale industrial applications.