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We present methods for β-selective 2-deoxy- and 2,6-dideoxyglucosylations of natural products, carbohydrates, and amino acids using bis-thiourea hydrogen-bond-donor catalysts. Disarming ester protecting groups were necessary to counter the high reactivity of 2-deoxyglycosyl electrophiles toward non-stereospecific S
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Peyton D. Beyer
Michael Martin Nielsen
Elias Picazo
Journal of the American Chemical Society
Harvard University
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Beyer et al. (Mon,) studied this question.
www.synapsesocial.com/papers/68e56386e2b3180350f00169 — DOI: https://doi.org/10.1021/jacs.4c11560