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Electrochemical reactivity is known to be dictated by the structure and composition of the electrocatalyst-electrolyte interface. Here, we show that optically generated electric fields at this interface can influence electrochemical reactivity insofar as to completely switch reaction selectivity. We study an electrocatalyst composed of gold-copper alloy nanoparticles known to be active toward the reduction of CO
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Francis M. Alcorn
Sajal Kumar Giri
Maya Chattoraj
Proceedings of the National Academy of Sciences
Northwestern University
University of Illinois Urbana-Champaign
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Alcorn et al. (Wed,) studied this question.
www.synapsesocial.com/papers/68e55ef6e2b3180350efc6a4 — DOI: https://doi.org/10.1073/pnas.2404433121
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