Accelerating Small Electron Polaron Dissociation and Hole Transfer at Solid–Liquid Interface for Enhanced Heterogeneous Photoreaction

) for oxygen atom transfer thanks to the donor-acceptor orbital interaction between Fe(IV) and organic pollutants. This work constructs a high-efficiency artificial photosynthetic system through synergistically eliminating electron localization and breaking hole transfer limitation at the solid-liquid interface for constructing high-efficiency artificial photosynthetic systems.