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= 1 DJ- and RP-perovskites with near-identical crystal structure, photoexcitation results in a slightly screened exciton with minimal structural relaxation and a retained binding energy of ∼0.29 eV in DJ-perovskites but strongly screened exciton polaron with a binding energy of ∼0.13 eV in RP-perovskites. Structural dynamics further highlight the rigid and harmonic lattice motion in DJ-perovskites, as opposed to the thermally activated anharmonic lattice in RP-perovskites, arising from their distinct bonding modes. Our study offers insights into modulating excited state properties in 2D perovskites, simulating the rational design of hybrid semiconductors with tailored properties and functionalities.
Lei et al. (Thu,) studied this question.