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attack, thereby facilitating selective C-F hydrodefluorination and subsequent fluorine immobilization. In a column flow reactor, silicate-modified nZVI efficiently removes perfluorooctanoic acid (PFOA) of concentrations ranging from 0.24 to 24 μmol/L with 75-92% defluorination efficiencies, 8 times higher than those of nZVI, generating environmentally friendly alkyl carboxylic acids as the primary products. Besides PFOA, this novel nZVI also realizes deep defluorination of other organofluorine compounds, including perfluorooctanesulfonates and fluoroquinolones, demonstrating its superior defluorination potential.
Liao et al. (Wed,) studied this question.