Creating Vacancy Strong Interaction to Enable Homogeneous High‐Throughput Ion Transport for Efficient Solid‐State Lithium Batteries

anions, while the electron-rich environment induced by sulfur atoms promotes the preferential degradation of bis(trifluoromethanesulfonyl)imide anions, ensuring uniform lithium deposition. This fosters the formation of inorganic nanocrystals on the lithium anode and effectively suppresses dendrite growth, enabling an ultra-long lifetime of over 5500 h in Li||Li symmetric cells. When paired with sulfurized polyacrylonitrile cathode, a pouch cell capacity of 0.524 Ah is achieved, demonstrating the effectiveness of a homogeneous, high-throughput Li-ions transport mechanism.