Intermolecular exchange interaction in bis-(phenoxy Schiff base) Co(ii) complexes: an in-depth insight into the magneto-structural nature of single-molecule magnets | Synapse
August 17, 2025
Intermolecular exchange interaction in bis-(phenoxy Schiff base) Co(ii) complexes: an in-depth insight into the magneto-structural nature of single-molecule magnets
Key Points
Exchange coupling in Co ii complexes shapes performance of single-molecule magnets, enhancing magnetic properties and stability.
EPR and SQUID techniques provided critical insights into the magnetic behavior and structural dynamics of Co ii complexes.
Analysis used SC-XRD, DFT, and ab initio methods to investigate polyhedral distortions affecting magneto-structural characteristics.
Findings suggest that understanding these interactions can lead to improved materials for magnetic applications.
Abstract
SC-XRD, multifrequency EPR, SQUID, DFT, and ab initio methods reveal exchange coupling and polyhedral distortion shaping the performance of pseudotetrahedral Co( ii ) single-ion magnets.