Reducing charge carrier transport losses, improving selectivity, and minimizing non-radiative recombination are essential for enhancing the efficiency and stability of perovskite/silicon tandem solar cells. We used a hybrid two-step perovskite deposition method that is compatible with industry-standard textured silicon, incorporating a perovskite surface treatment based on 1,3-diaminopropane dihydroiodide. The interaction of this molecule with the perovskite surface increased the majority charge carrier concentration at the electron-selective contact, which reduced interfacial recombination. Simultaneously, this field-effect passivation increased the electron concentration across the entire intrinsic perovskite absorber, which increased conductivity and reduced transport losses. Combined, this yields high-performance, fully-textured perovskite/silicon tandem solar cells, achieving a 1-sun AM1.5G conversion efficiency of 33.1% with an open-circuit voltage of 2.01 volts, and an extended outdoor stability in the Red Sea Coast.
Er‐raji et al. (2025) studied this question.