Acid mine drainage (AMD) poses significant environmental and health risks due to its high acidity and elevated metal and sulfate contents. Previous studies have primarily focused on short-term AMD monitoring, with limited attention paid to long-term, spatially resolved datasets and predictive modeling. In this 3.5-year study, six wells down-stream of a mine waste rock pile were monitored, and 132 sets of associated water quality (AWQ), geological (GEO), and climate history (CH) parameters were compiled to develop predictive models for Fe, Cu, and Zn concentrations. Random forest (RF), extreme gradient boosting (XGBoost), and support vector machine (SVM) algorithms were applied using different combinations of input variables. The combined AWQ-GEO-CH dataset achieved the best overall performance, with XGBoost yielding the highest R2 values for Fe (0.81) and Cu (0.77), and SVM performing best for Zn (0.94). CH variables, particularly precipitation and evaporation over 60-day periods, strongly influenced metal concentrations by driving hydrological and solute redistribution processes. AWQ parameters, especially F− and S2−, were key predictors for Fe and Zn and ranked second for Cu, likely due to shared upstream sources and coupled geochemical processes such as FeF3 dissolution. The most impactful GEO factor was the installation of a vertical barrier, which reduced metal concentrations by 73–80%. These findings highlight the value of integrating multi-source datasets with ML for long-term AMD prediction and management.
Wu et al. (Tue,) studied this question.