We derive effective equations of motion governing the dynamics of sharp interfaces in phase-separated binary mixtures driven by spatio-temporal modulations of their material properties. We demonstrate, in particular, that spatial heterogeneities in the surface tension induce an effective capillary force that drives the motion of interfaces, even in the absence of hydrodynamics. Applying our sharp interface model to quantify the dynamics of thermophoretic droplets, we find that their deformation and transport properties are controlled by a combination of bulk and capillary forces, whose relative strength depends on droplet size. Strikingly, we show that small thermophobic droplets -- composed of a material with a positive Soret coefficient -- can spontaneously migrate towards high-temperature regions as a result of capillary forces.
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Jacopo Romano
Ramin Golestanian
Benoît Mahault
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Romano et al. (Mon,) studied this question.
www.synapsesocial.com/papers/68de84bf5b556a9128e1bb19 — DOI: https://doi.org/10.48550/arxiv.2506.19029