The deterministic and time-reversal symmetric dynamics of isolated quantum systems is at odds with irreversible equilibration observed in generic thermodynamic systems. Standard approaches at a reconciliation employ subjective restrictions on the space of observables or states and do not explain how a single macroscopic quantum system achieves equilibrium dynamically. We instead argue that quantum theory is an effective theory and requires corrections to accurately describe systems approaching the thermodynamic limit. We construct a stochastic extension of quantum theory which is practically identical to quantum mechanics for microscopic systems, yet allows single, isolated macroscopic systems to objectively thermalize, generically. A fluctuation-dissipation relation guarantees physical consistency including norm preservation, energy conservation, no superluminal signalling and the emergence of microcanonical equilibrium. We further discuss the inclusion of objective collapse, thereby realizing a falsifiable theory of spontaneous universal irreversibility which describes the quantum-to-classical crossover dynamics of macroscopic quantum systems. This model admits spontaneous symmetry breaking, quantum state reduction and objective quantum thermalization for individual systems while realizing an emergent hybrid, Born-Maxwell-Boltzmann-Gibbs-microcanonical distribution for ensembles.
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Aritro Mukherjee
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Aritro Mukherjee (Tue,) studied this question.
www.synapsesocial.com/papers/68e7f0af2d7e30942762c7c1 — DOI: https://doi.org/10.48550/arxiv.2504.16197