Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands

In the coordination chemistry of heavier tetrylenes (: ER2, where E = Si, Ge, Sn, Pb), chelating P, N-donor ligands occupy a privileged position, though phosphinoamido ligands, R2P-NR'-, have been barely investigated. Herein, we report the synthesis and structural characterization of such complexes, whose structures drastically differ depending on the group 9 metal precursor used. Strained four-membered P-N-Ge-M metallacycles (M = Rh, Ir) are produced from the reaction of phosphinoamido germylenes with MCl2Cp*2 precursors (Cp* = η5-C5Me5). At variance, MCl- (COD) 2 dimers are not broken apart; instead, they afford bimetallic species featuring bridging phosphinoamido-germyl and chloride ligands between the two metals. All new compounds were isolated on a preparative scale and spectroscopically characterized and their structures confirmed by X-ray diffraction. Computational studies support the σ-donor character of the Ge-M interaction and the absence of significant π-backbonding.