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Isolation of arylhalodiphosphenes: periodic trends in R–PP–X bonding (X = Cl, Br, I) | Synapse

February 26, 2026Open Access

Isolation of arylhalodiphosphenes: periodic trends in R–PP–X bonding (X = Cl, Br, I)

JWJohn S. WengerUniversity of Oxford NGNina GaschikLudwig-Maximilians-Universität München WRWilliam J. RoweUniversity of Oxford

Key Points

The aim is to synthesize arylhalodiphosphenes and explore the periodic trends in their bonding characteristics.
Synthesis of arylhalodiphosphenes using arylhalides as precursors
Characterization of the bonding trends based on halogen type (Cl, Br, I)
Successfully synthesized monomeric arylhalodiphosphenes
Identified variations in bonding trends among different halogens.

Abstract

Aryldiazonium halides have served as important synthetic intermediates for over a century. Herein, we report the synthesis of compositionally related monomeric arylhalodiphosphenes.

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Cite This Study

Wenger et al. (Thu,) studied this question.

synapsesocial.com/papers/699fe3f995ddcd3a253e81b2 https://doi.org/https://doi.org/10.1039/d6sc00723f