The transformations of dichloromethyladamantane and its derivatives in strongly acidic media have been studied. It has been established that the nitroxylation reaction is not accompanied by nitrolysis of the dichloromethyl group. A number of products of substitution of dichloromethyladamantane at the 3rd position were obtained under the conditions of generating a tertiary carbenium cation and it was found that the dichloromethyl group was retained in the structure of all products, which allows their further modification.
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V. A. Shiryaev
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V. A. Shiryaev (Wed,) studied this question.
www.synapsesocial.com/papers/69a287690a974eb0d3c030af — DOI: https://doi.org/10.7868/s3034630425060039