Water Absorption and Mechanical Durability of Ramie–Flax Fibre-Reinforced Epoxy Hybrid Composites

Natural fibre hybrid composites have gained attention as cleaner alternatives to synthetic glass fibre systems due to their renewable feedstocks and inherent density advantage. However, moisture ingress degrades fibre–matrix integrity and mechanical performance, making durability a critical design constraint. This study systematically investigates the water absorption kinetics and post-immersion mechanical property retention in ramie–flax/epoxy hybrid composites across four fibre loadings (10–40 wt.%), with the ramie-to-flax weight ratio fixed at 1:1 in all formulations. Tensile, flexural, and impact properties were evaluated under dry and saturated conditions; Fickian diffusion kinetics were analysed to quantify moisture transport parameters; and fracture surfaces were examined by SEM. A density-based material efficiency analysis quantified the lightweighting benefit relative to equivalent synthetic glass/epoxy composites. Water absorption increased monotonically with fibre content; all formulations reached equilibrium after approximately 120 h. The 30 wt.% composite achieved dry-state tensile, flexural, and impact strengths of ca.49 MPa, ca.58 MPa, and 2.82 kJ/m2 respectively, retaining ca.78%, ca.69%, and ca.82% after full saturation, superior to all other loadings. These results establish 30 wt.% as the optimal fibre loading for moisture-exposed semi-structural applications, supporting the adoption of ramie–flax composites within a cleaner manufacturing framework.