Forcing the Side-on π-Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2-Bis(2-(diisopropylarsaneyl)-4-(trifluoromethyl)phenyl)Ethyne. | Synapse
May 5, 2026
Forcing the Side-on π-Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2-Bis(2-(diisopropylarsaneyl)-4-(trifluoromethyl)phenyl)Ethyne.
Key Points
The central aim is to explore the chelation of technetium using alkyne donors.
Utilized the ligand 1,2-Bis(2-(diisopropylarsaneyl)-4-(trifluoromethyl)phenyl)Ethyne.
Focused on the structural implications of alkyne donors on technetium coordination.
Confirmed stable chelation of technetium at the tracer level.
Validated the potential of alkyne donors as effective building blocks for technetium coordination.
Abstract
Tc proves the viability of alkyne donors as building blocks for stable chelation of technetium at the tracer level.