Supramolecular Radical Chemistry: Self-Assembly and Spin Regulation

Key Points

• The research aims to explore strategies for stabilizing and regulating radicals through supramolecular approaches.
• Systematic review of advancements in supramolecular radical chemistry.
• Analysis of molecular recognition and spin regulation patterns in host-guest systems.
• Examination of applications in catalytic conversion and self-assembly monitoring.
• Identified mechanisms for radical stabilization and controlled generation.
• Demonstrated the relationship between structure, properties, and functionalities of supramolecular radicals.
• Outlined key challenges and future directions for molecular design and system optimization.

Abstract