Condensates are ubiquitous to all Solar System planets with significant (>10, mbar) atmospheres. The same is true for most exoplanets with characterised atmospheres, with even ultra-hot exoplanets being able to form clouds on their cooler nightsides. One high-interest condensate is titanium, a highly refractory element that as an oxide (TiO) is a potent optical absorber long believed to be a driver of thermal inversions in highly irradiated exoplanet atmospheres. Observations have shown that some ultra-hot Jupiters have strong thermal inversions despite being significantly Ti-depleted, likely due to cold trapping, raising doubts about whether TiO is the main cause of their inverted temperature structures. Our aim was to retrieve the titanium-to-iron ratio of the dayside atmosphere of the ultra-hot Jupiter WASP-189b to determine whether the full titanium budget is accounted for in the gas phase. We analysed thermal emission observations of WASP-189b taken with the HARPS and NIRPS spectrographs using different atmospheric retrieval prescriptions to infer the planet's atmospheric thermal structure and composition. We observed Fe and Ti signals in cross-correlation and measured a sub-solar Ti/Fe ratio for WASP-189b using both free and chemical equilibrium retrieval approaches. We find the Ti/Fe of the planetary atmosphere to be between 28% and 81% (1-σ bounds) that of the stellar value. The slight underabundance of Ti with respect to Fe on the dayside atmosphere of WASP-189b suggests that some titanium is missing from the gas phase, potentially due to a partial nightside cold trap. In the context of the ultra-hot Jupiter population, the onset of titanium in exoplanetary atmospheres appears to occur progressively, coinciding not with when thermal inversions begin but rather when the vapourisation threshold of titanium is reached on the nightside.
Pelletier et al. (Wed,) studied this question.