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August 17, 2025Green Chemistry9 citations

Photoelectrocatalytic Heteroarene C(sp2)-H Borylation

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LSLina SongJZJinliang ZhuangPXPeng Xiong

Key Points

  • Direct C(sp2)–H borylation of (hetero)arenes achieved using photoelectrocatalytic methods, indicating significant advancement in C–H functionalization.
  • Key evidence includes successful borylation reactions demonstrating effective radical formation under controlled conditions.
  • This study utilizes a photoelectrocatalytic strategy addressing previously unmanageable challenges in radical borylation methods.
  • This new method highlights the potential for expanding C–H borylation techniques in organic synthesis, enabling further applications.

Abstract

Boryl radical-mediated C–H borylation remains underdeveloped due to challenges in the formation and control of boron-centered radicals. Herein, we report a photoelectrocatalytic strategy for direct C(sp²)–H borylation of (hetero)arenes using...

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Cite This Study

Song et al. (2025) studied this question.

synapsesocial.com/papers/68a36ddf0a429f7973331314https://doi.org/10.1039/d5gc03231h
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