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September 10, 2025

Synthesis and Chiroptical Property of Chiral Heteroatom‐Embedded Zigzag‐Type Hydrocarbon Belts

Key Points

The synthesis process yields diverse chiral hydrocarbon belts with unique structures and properties.
Palladium-catalyzed reactions are utilized for forming C–N bonds with chiral amines, resulting in chiral nanobelts.
The resulting nanobelts demonstrate intriguing chiroptical properties, emphasizing their potential applications.
Insights into chiral transfer processes highlight new pathways for designing synthetic chiral nanomaterials.

Abstract

Herein, the synthesis of diverse chiral O/N‐doped zigzag hydrocarbon belts based on bridging of the fjords of resorcin4arene and resorcin6arene derivatives with chiral amines through palladium‐catalyzed intermolecular CN bond formation reactions is reported. The resulting nanobelts exhibit unique chiral cavity structures and demonstrate intriguing chiroptical properties. Furthermore, a chiral transfer process from small molecule amines to the hydrocarbon nanobelts, offering new insights for designing and synthesizing novel chiral nanobelts is uncovered.

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Cite This Study

Jin et al. (Fri,) studied this question.

synapsesocial.com/papers/68c1c32754b1d3bfb60f1317 https://doi.org/https://doi.org/10.1002/ejoc.202500755

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