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Abstract As ammonia continues to gain more and more interest as a promising hydrogen carrier compound, so does the electrochemical ammonia oxidation reaction (AmOR). To avoid the liberation of H 2 in a reverse Haber–Bosch reaction under release of the energetically more favorable N 2, we propose the oxidation of ammonia to value‐added nitrite (NO 2 −), which is usually obtained during the Ostwald process. We investigated the anodic oxidation of gaseous ammonia directly supplied to a gas diffusion electrode (GDE) using a variety of compositionally different multi‐metal catalysts coated on Ni foam under the simultaneous formation of H 2 at the cathode. This will double the amount of H 2 per ammonia molecule while applying a lower overpotential than that required for water electrolysis (1. 4–1. 8 V vs. RHE at 50 mA ⋅ cm −2). A selectivity study demonstrated that some of the catalyst compositions were able to produce significant amounts of NO 2 −, and further investigations using the most promising catalyst composition Ni f AlCoCrCuFe integrated within a GDE demonstrated up to 88 % Faradaic efficiency for NO 2 − at the anode coupled to close to 100 % Faradaic efficiency for the cathodic H 2 production.
Cechanaviciutè et al. (Mon,) studied this question.